Catalytic Enantioselective Reactions Part 7. Synthesis of New β-Aminoalcohols Derived from α-D-Glucose as Chiral Catalysts for the Catalytic Enantioselective Addition of Diethylzinc to Aldehydes |
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| Authors: | Byung Tae Cho Namdu Kim |
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| Institution: | Department of Chemistry , Hallym University , Chunchon, 200–702, Republic of Korea |
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| Abstract: | A series of new 1, 2-O-isopropylidene-3-O-methyl-6-deoxy-6-N, N-dialkylamino-α-D-glucofuranoses 1 and 1, 2-O-isopropylidene-3, 6-dideoxy-6-N, N-dialkylamino-α-D-glucofuranoses 1′ were prepared from α-D-glucose and their enantiose-lectivities compared as chiral catalysts for the ethylation of benzaldehyde and heptanal with diethylzinc. |
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