Lewis Acid Mediated Addition of Aminoketene Dithioacetals to α, β-Unsaturated Ketones |
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Authors: | Philip C Bulman Shaun A Harkin Allan P Marchington |
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Institution: | 1. Robert Robinson Laboratories, Department of Chemistry , University of Liverpool , P.O. Box 147, Liverpool, L69 3BX, U.K.;2. Shell Research Ltd., Sittingbourne Research Centre , Sittingbourne, Kent, ME9 8AG, U.K.;3. Robert Robinson Laboratories, Department of Chemistry , University of Liverpool , P.O. Box 147, Liverpool, L69 3BX, U.K. |
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Abstract: | Lewis acids catalyse the addition of aminoketene dithioacetals to α-β-unsaturated ketones to give 1,5-diketones after hydrolytic work-up. |
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