Synthesis of Thiols via Palladium Catalyzed Methanolysis of Thioacetates with Borohydride Exchange Resin |
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Authors: | Jaesung Choi Nung Min Yoon |
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Affiliation: | Department of Chemistry , Sogang University , Seoul, 121-742, Korea |
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Abstract: | Various thiols are prepared quantitatively from the corresponding thioacetates via Pd catalyzed methanolysis with borohydride exchange resin under a mild and neutral conditions. One-pot synthesis of thiols from alkyl halides through the formation of alkyl thioacetates using thioacetate exchange resin followed by methanolysis is also described. |
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