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A Facile Route to Convert Acetylacetone into Other β-Diketones with Acyl Chlorides Promoted by Samarium Triiodide |
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| Authors: | Wenying Hao Yongmin Zhang Taokai Ying Pin Lu |
| Institution: | Department of Chemistry , Hangzhou University , Hangzhou, 310028, P.R. China |
| Abstract: | Reaction of acetylacetone with acyl chlorides in the presence of SmI3 gave β-diketones RCOCH2COCH3 (I) or RCOCH2COR (II) in good yields under mild and neutral conditions. |
| Keywords: | |