Synthesis of Phenacyl Esters by Using PTC and Dibenzo-[18]-crown-6 |
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| Authors: | Suman J Jagdale Sucheta V Patil Manikrao M Salunkhe |
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| Institution: | 1. Dept. of Chemistry , Shivaji University , Kolhapur, 416 004, INDIA;2. Dept. of Chemistry , The Institute of Science , 15, Madam Cama Road, BOMBAY, 400 032, INDIA |
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| Abstract: | In view of the importance of phenacyl esters as a protecting groups, a simple and efficient method is now reported here for synthesis of phenacyl esters in quantitative yield and high purity under mild reaction condition by using phase transfer catalyst and dibenzo-18]-crown-6. It has been demonstrated that the spatial coordination of ion and ligand cavity plays important role in using crown ethers. |
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