Halide Exchange at Vinylic Position Catalyzed by Copper (1)halide Complexes of Trivalent Phosphorus |
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| Authors: | George Axelrad Surin Laosooksathit Robert Engel |
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| Institution: | Doctoral Program in Chemistry , The City University of New York, Queens College , Flushing, New York, 11367 |
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| Abstract: | In the course of our recent studies of the direct synthesis of vinylic phosphonates from vinylic halides with copper(I) halide complexes of trialkyl phosphites,1 there was uncovered an accompanying facile halogen exchange reaction. This prompted a further examination of this exchange reaction employing a series of copper(I) halide complexes of triphenyl phosphite and triphenylphosphine. |
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