A Convenient Synthesis of 2-Styrylchromones by Modified Baker-Venkataraman Transformation Using Phase Transfer Catalysis |
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| Authors: | J K Makrandi Vandna Kumari |
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| Institution: | Department of Chemistry , Maharshi Dayanand University , Rohtak, 124001, India |
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| Abstract: | Condensation of 2-hydroxyacetophenones 1 with cinnamic anhydrides 2 in the presence of tetra-n-butyl ammonium hydrogen sulphate in benzene-aqueous potassium carbonate biphase medium give 1-(2-hydrcxyphenyl)-5-phenyl-4-pentene-l, 3-diones 3 which on cyclodehydration using p-toluene sulphonic acid in dimethylsulphoxide give 2-styrylchromones 4 in high yields. |
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