1,3-Diene-Containing Phase Transfer Catalysts and Their Removal From Solution by a Diels-Alder Reaction with an Immobilized Triazolinedione Dienophile |
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Authors: | John F W Keana David D Ward |
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Institution: | Department of Chemistry , University of Oregon , Eugene, Oregon, 97403 |
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Abstract: | 8E,10E-Dodecadienyl-tri-n-butylamonium and -tri-n-butylphosphonium methanesulfonates were prepared and shown to be effective phase transfer catalysts. After reaction the catalysts can be removed quantitatively from the organic phase by addition of a silica gelimmobilized triazolinedione dienophile followed by filtration. |
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