Silafunctional Compounds in Organic Synthesis. XXXVII. Metalated (Allyl) Aminosilanes: Regioselective Coupling with Alkyl Halides to (E)-1-Alkenylsilanes with a Functional Group on Silicon |
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| Authors: | Kohei Tamao Eiji Nakajo Yoshihiko Ito |
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| Affiliation: | Department of Synthetic Chemistry, Faculty of Engineering , Kyoto University , Kyoto, 606, Japan |
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| Abstract: | (E)-1-Alkenylsilanes with an amino or an alkoxy group on silicon can be conveniently synthesized by regioselective coupling of a potassium reagent derived from an allyl(amino)silane with alkyl halides. |
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