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Carbonyl Regeneration from Oximes and Semicarbazones by Trimethylchlorosilane-Dimethylsulphoxide
Authors:Franco Ghelfi  Romano Grandi  Ugo M Pagnoni
Institution:Dipartimento di Chimica dell Università , via Campi 183, I-41100, Modena, Italy
Abstract:Treatment of oximes and semicarbazones of saturated and α,β-unsaturated ketones and aldehydes with trimethylchlorosilane-dimethyl sulphoxide in dry acetonitrile affords the corresponding carbonyl compounds in excellent yields under mild conditions.
Keywords:
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