Palladium-Catalyzed Preparation of Dialkyl Allylphosphonates. A New Preparation of Diethyl 2-Oxoethylphosphonate |
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| Authors: | R. Malet M. Moreno-Mañas R. Pleixats |
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| Affiliation: | Department of Chemistry , Universitat Autònoma de Barcelona , Bellaterra, 08193, Barcelona, Spain |
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| Abstract: | Palladium-catalyzed Michaelis-Arbuzov reaction of allyl acetates with trialkyl phosphites affords dialkyl allylphosphonates. Diethyl 2-oxoethylphosphonate is efficiently prepared by ozonization of diethyl allylphosphonate. |
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