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New Efficient Synthesis of Methyl Trans-2-Aryl (or Hetaryl)-1-Benzamidocyclopropancarboxylates
Authors:Javier Blasco  Carlos Cativiela  M Dolores Diaz de Villegas
Institution:Institute de Ciencia de los Materiales de Aragón. Department of Organic Chemistry , University of Zaragoza , 50009, Zaragoza, Spain
Abstract:Methyl trans-2-aryl(or hetaryl)-1-benzamidocyclopropancarboxylates can be easily obtained by thermal decomposition of trans-4-aryl(or hetaryl)-3-benzamido-3-carbomethoxy-Δ1-pyrazolines synthesized by 1,3-dipolar cycloaddition of diazomethane with methyl E-3-aryl(or hetaryl)-2-benzamido-2-propenoates.
Keywords:
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