A Convenient Synthesis of Allyltrimethylsilanes from Allylic Phosphates |
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| Authors: | Janice Gorzynski Smith Susan L Henke Elizabeth M Mohler Linda Morgan N Ivy Rajan |
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| Institution: | Department of Chemistry, Carr Laboratory , Mount Holyoke College , South Hadley, Massachusetts, 01075 |
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| Abstract: | Treatment of an allylic phosphate with trimethylsilyllithium or trimethylsilylcopper prepared from one equivalent of trimethylsilyllithium and copper(I) iodide] affords allyltrimethylsilanes in good - excellent yields with high stereoselectivity. |
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