New Syntheses of Geiparvarin and 2,5-Dimethyl-3(2H)-furanone Via Co2 Mediated Bond Reorganization |
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Authors: | Y. Inoue K. Ohuchi S. Imaizumi H. Hagiwara H. Uda |
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Affiliation: | 1. Department of Engineering Science , Faculty of Engineering, Tohoku University , Aoba, Sendai, 980, Japan;2. Chemical Research Institute of Non-Aqueous Solutions, Tohoku University , Katahira, Sendai, 980, Japan |
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Abstract: | A new synthesis of 3(2H)-furanones from 4-hydroxy-2-alkyn-1-one derivatives via CO2 mediated bond reorganization has been developed to the preparation of an antitumor agent, geiparvarin and a constituent of flavors, 2,5-dimethyl-3(2H)-furanone. |
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Keywords: | Aromatic aldehydes 5,5-Dimethyl-1,3-cyclohexanedione Condensation reaction |
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