A Simple Synthesis of (R)(S)(E)-3,7-Dimethyl-2-octene-1,8-dioc Acid,a Copulation Release Pheromone Component of the Azuki Bean Weevil |
| |
| Authors: | Elisabetta Adorni Fontana Adriano Carpita Elena Rossi |
| |
| Affiliation: | Dipartimento di Chimica e Chimica Industriale , Università di Pisa , Via Risorgimento 35, I-56126, Pisa, Italy |
| |
| Abstract: | (R)(S)(E)-3,7-dimethyl-2-octene-1,8-dioic acid, (R)(S)(E)-1, also named callosobruchusic acid, has been synthetized in five steps using a simple reaction sequence based on the zirconium-catalyzed methylalumination of commercially available 4-pentyn-1-ol, 2a, or its O-tert-butyldimethylsilyl ether, 2b. |
| |
| Keywords: | |
|
|
