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Photochemical Rearrangements of Chiral Bicyclo[2.2.2]oct-5-en-2-Ones1 |
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| Authors: | A Srikrishna S Danieldoss |
| Institution: | Department of Organic Chemistry , Indian Institute of Science , Bangalore, 560 012, India |
| Abstract: | Photochemical oxadi-π-methane rearrangement (1,2-acyl shift) of the chiral bicyclo2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6 , whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively. |
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