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Stellarins F and G, two new cyclopeptides from Stellaria yunnanensis
作者姓名:ZHAO  Yu-Rui WANG  Xian-Kai
作者单位:ZHAO,Yu-Rui WANG,Xian-KaiDepartment of Medicinal Chemistry of Natural Products,School of Pharmacy,West China University of Medical Sciences,Chengdu,Sichuan 610041,ChinaZHOU,Jun CHENG,Chang-XiangLaboratory of Phytochemistry,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming,Yunnan 650204,ChinaHUANG,Xiao-Lin WU,Hou-MingState Key Laboratory of Bio-Organic Chemistry & Natural Products,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
基金项目:Project supproted by grants from Laboratory of Phytochemistry,Kunming Institute of Botany,Chinese Academy of Sciences and State Key Laboratory of Bio-Organic Chemistry & Natural Products,Chinese Academy of Sciences.
摘    要:In the previous papers,we reported the structural elucidation of stellarins A-E,fivenew cyclopeptides from the fresh roots of Stellaria yunnanensis Franch.Further chemical study on this plant led to the isolation of two other new cyclopeptides named stellarins F(l) and G(2).By a combination of 2D-NMR,enzymatic degradation and FABMS,their structures were established to be cyclo(Gly-Ala-Gly-Ser-Pro-Trp-Phe-Pro) and cyclo(Gly-Ala-Tyr-Leu-Ala),respectively.


Stellarins F and G, two new cyclopeptides from Stellaria yunnanensis
ZHAO,Yu-Rui WANG,Xian-Kai.Stellarins F and G, two new cyclopeptides from Stellaria yunnanensis[J].Chinese Journal of Chemistry,1995,13(6):552-557.
Authors:ZHAO  Yu-Rui WANG  Xian-Kai
Institution:ZHAO,Yu-Rui WANG,Xian-KaiDepartment of Medicinal Chemistry of Natural Products,School of Pharmacy,West China University of Medical Sciences,Chengdu,Sichuan 610041,ChinaZHOU,Jun CHENG,Chang-XiangLaboratory of Phytochemistry,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming,Yunnan 650204,ChinaHUANG,Xiao-Lin WU,Hou-MingState Key Laboratory of Bio-Organic Chemistry & Natural Products,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
Abstract:In the previous papers,we reported the structural elucidation of stellarins A-E,fivenew cyclopeptides from the fresh roots of Stellaria yunnanensis Franch.Further chemical study on this plant led to the isolation of two other new cyclopeptides named stellarins F(l) and G(2).By a combination of 2D-NMR,enzymatic degradation and FABMS,their structures were established to be cyclo(Gly-Ala-Gly-Ser-Pro-Trp-Phe-Pro) and cyclo(Gly-Ala-Tyr-Leu-Ala),respectively.
Keywords:Stellaria yunnanensis  caryophyllaceae  cyclopeptides  stellarins F and G
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