The first solid phase synthesis of pincer palladium complexes |
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Authors: | Kozlov Vladimir A Aleksanyan Diana V Korobov Mikhail V Avramenko Natalya V Aysin Rinat R Maloshitskaya Olga A Korlyukov Alexander S Odinets Irina L |
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Institution: | A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova Street, Moscow, 119991, Russia. |
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Abstract: | Both dimeric μ-chlorine bridged and monomeric bidentate Pd(II) complexes with SCN hybrid pincer-type ligands, bearing thiophosphoryl group and imine moiety of the benzothiazole ring as coordination arms, formed in the reaction with (PhCN)(2)PdCl(2) under kinetic control (20 °C, dichloromethane solution) were readily converted into the corresponding SCN pincer complexes via solid phase synthesis (neat, 200 °C, 15 min). The synthesis of pincer complexes can be performed also by heating (200 °C, 5 min) of a homogeneous mixture of the initial reactants, namely, the ligand and (PhCN)(2)PdCl(2), obtained by manual grinding in a mortar. The efficacy of solid phase approaches is comparable with the analogous synthesis in solutions under severe conditions. |
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