Controlling state of breathing of two isoreticular microporous metal-organic frameworks with triazole homologues |
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| Authors: | Zhi-Qiang Jiang Gui-Yuan Jiang Fei Wang Zhen Zhao Jian Zhang |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (P.R. China); State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249 Beijing, (P.R. China). |
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| Abstract: | Breathing effect: Using two triazole homologues (1H-benzotriazole and 1,2,3-1H-triazole), two isoreticular microporous Zn-benzenedicarboxylate frameworks 1 and 2 with reverse dynamic features are presented, in which different sized triazole ligands effectively control the state of breathing of two flexible frameworks. |
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