Synthesis,crystal structure and spectroscopic properties of a copper(II) complex of the Schiff-base derived from picolinaldehyde N-oxide and 4-aminoantipyridine |
| |
| Authors: | Liang Hong Yu Qing Hu Rui-Xiang Zhou Zhong-Yuan Zhou Xiang-Ge |
| |
| Affiliation: | (1) Department of Chemistry, Guangxi Normal University, Guilin, Guangxi, 541004, P.R. China;(2) Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, Sichuan, 610041, P.R. China |
| |
| Abstract: | The Schiff-base (PNOAAP) derived from picolinaldehyde N-oxide and 4-aminoantipyrine, and its copper(II) complex: [Cu(PNOAAP)2(EtOH)2]2(ClO4)4(1) has been prepared and characterized by elemental analysis, i.r., 1H-n.m.r. spectrum, and single crystal X-ray crystallographic determination. The PNOAAP ligand isomerizes from trans to cis after chelating to copper(II). |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
