Magnetic isotope effect of tin and isotope exchange in the reactions of organotin compounds |
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Authors: | A V Podoplelov Sen Chel Su R Z Sagdeev M S Shtein V M Moralev V I Gol'danskii Yu N Molin |
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Institution: | (1) Institute of Chemical Kinetics and Combustion, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk;(2) Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk;(3) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions Magnetic isotope effects from tin are not observed during the isotope analysis of the products from reactions involving trimethylstannyl radicals. One of the possible reasons for this is the demonstrated presence of degenerate exchange processes between the initial compounds and the products during the reaction.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2207–2211, October, 1985. |
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