Synthesis and reactivity of a 9-membered azaenediyne: importance of proximity effect in N-alkylation |
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| Authors: | Roy Sandip Kumar Basak Amit |
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| Affiliation: | Bioorganic Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur, India. |
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| Abstract: | Synthesis of a 9-membered azaenediyne has been achieved for the first time via intramolecular N-alkylation; the importance of proximity of the reacting centres via cobalt carbonyl complexation of the acetylenic moiety and not the activation of propargylic carbon has been demonstrated. |
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