Time resolved fluorescence spectroscopy of Eu(III) complexation with alpha-hydroxy isobutyric acid |
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Authors: | Jain A Mohapatra M Godbole S V Tomar B S |
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Affiliation: | Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India. |
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Abstract: | Complexation of Eu(III) with alpha-hydroxy isobutyric acid (HIBA), a model compound of humic acid, has been studied by time resolved fluorescence spectroscopy. The ratio of fluorescence intensity of the two peaks at 616 and 592 nm (I(616/592)) was found to increase with increasing ligand to metal ratio. The I(616/592) data was used to deduce the stability constant of Eu-HIBA complexes of the type ML(i) (i=1-3). The formation of multiple ligand complexes was also corroborated by lifetime data which was found to increase with increasing [HIBA]/[Eu] ratio thus indicating replacement of coordinated water molecules by HIBA. |
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