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Mise en evidence d''un intermediare cationique hydridoponte [1,5] lors de l''action du reactif de olah sur le phenyl-‘ aza-9 bicyclo [6.1.0.] nonane |
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| Authors: | G. Haufe S. Lacombe A. Laurent C. Rousset |
| Affiliation: | a Laboratoire de Chimie Organique III - ERA CNRS 611, Université Claude Bernard-Lyon I 43, Boulevard du 11 November 1918 69622 Villeurbanne Cedex - France- b Sektion Chemie, Karl-Marx-Universität, DDR 7010 Leipzig, Liebigstrasse 18, German Democratic Republic. |
| Abstract: | The addition of hydrogen fluoride to 1-phenyl-9-azabicyclo [6.1.0] nonane gives two fluoroamines (52 %). The structures were established by n.m.r. techniques to be cis-2-fluoro-2-phenylcyclooctylamine and c-6-fluoro-c-2-phenylcyclooctyl-r-1-amine. A hydrido-bridged cation is likely the intermediate of the reaction. |
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