Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate |
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Authors: | Bhat Vikram Rawal Viresh H |
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Institution: | Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637, USA. |
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Abstract: | Described is a concise synthesis of the 20,21-dihydro analog of N-methylwelwitindolinone B isothiocyanate, wherein a cationic homoallyl to cyclopropylmethyl rearrangement is circumvented by hydrogenation of the offending double bond. |
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