New approach for the synthesis of isoxazoline-N-oxides |
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| Authors: | Kunetsky Roman A Dilman Alexander D Ioffe Sema L Struchkova Marina I Strelenko Yury A Tartakovsky Vladimir A |
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| Institution: | N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation. |
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| Abstract: | A strategy for the synthesis of isoxazoline-N-oxides (cyclic five-membered nitronates) from primary nitro compounds and olefins is described. The key step of the process involves 1,3-dipolar cycloaddition of corresponding 1-bromosilyl nitronates with alkenes. reaction: see text] |
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