Synthesis of 1-ethylpyrrolidone-2 by hydrogenation of 1-vinylpyrrolidone-2 over a Pd/C catalyst |
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Authors: | I L Simakova V A Semikolenov |
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Institution: | (1) Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Division, 630090 Novosibirsk, Russia |
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Abstract: | A selective catalytic system for the hydrogenation of 1-vinylpyrrolidone-2 (VP) to 1-ethylpyrrolidone-2 (EP) is found. The
factors responsible for the formation of by-products in the conversion of VP are studied. The presence of acid sites or radical
species in a catalytic system results in the fast polymerization of VP. The resulting by-product, poly vinylpyrrolidone, may
deactivate the hydrogenation catalyst by surface blocking. VP can be hydrogenated to EP under mild conditions and with a high
selectivity using a palladium catalyst supported on a porous carbon material Sibunit. The kinetics of VP hydrogenation over
the Pd/C catalyst is studied. |
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Keywords: | |
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