Polymerization of substituted olefins initiated by organometallic compounds of titanium (IV) |
| |
| Authors: | C Blandy D Gervais |
| |
| Institution: | Laboratoire de Chimie de Coordination du CNRS associé à l''Université Paul Sabatier, 205 route de Narbonne, 31030 Toulouse-Cedex, France |
| |
| Abstract: | Polymerization tests were carried out in homogeneous systems on various substituted olefins CH2=CRZ (R = H or CH3; Z = CN, COOR, C6H5 or OCOR) with compounds of titanium (IV) Ti X4?x Yx (X and/or Y = Cl, OR, NR2, C5H5, OCH2 CF3, CH3, C6H5 …) or with the bimetallic complex CH3Ti(OR)3, Al(CH3)3. The activity of the initiator varies with the co-ordination environment of the titanium and to a considerable extent with the functional groups linked to the olefin. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
