Iodination and Chlorination of Aromatic Polycyclic Hydrocarbons with Iodine Monochloride in Aqueous Sulfuric Acid |
| |
| Authors: | V K Chaikovskii V D Filimonov |
| |
| Institution: | (1) Tomsk Polytechnic University, Tomsk, 634004, Russia |
| |
| Abstract: | Polycyclic aromatic hydrocarbons when treated with iodine monochloride in water solutions of sulfuric acid afford iodo- and chloroderivatives. Biphenyl, fluorene, acenaphthene, 1-nitronaphthalene undergo iodination. Naphthalene furnishes a mixture of iodo- and chloroderivatives, prevailing the latter. Anthracene and phenanthrene provide only chlorinated products. The iodine monochloride in the sulfuric acid is a stronger iodinating agent than in acetonitrile. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
