| Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates |
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| 作者姓名： | TAYEBEE Reza ALIZADEH Mohammad Hassan |
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| 作者单位： | [1]Department of Chemistry, Sabzevar University, Sabzevar, 397, lran [2]Department of Chemistry, Ferdowsi University, Mashhad, 91779, lran |
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| 摘 要： | An environmentally benign oxygenation protocol was developed for selective oxidation of some types of aromatic and aliphatic sulfides in good to excellent yields utilizing 34% hydrogen peroxide catalyzed by simple heteropolyoxometalates in normal drinking water at room temperature. The catalysts could be recovered and reused for at least seven reaction cycles under the described reaction conditions without considerable loss of reactivity. This procedure introduced a new insight into the use of simple heteropolyanions as recoverable catalysts for the oxidation of organic sulfides by an environmentally acceptable protocol. Keywords
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| 关 键 词： | 杂多酸 氧化作用 催化作用 硫化物 |
| 收稿时间： | 2006-11-24 |
| 修稿时间： | 2006-11-24 |
Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates |
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| TAYEBEE Reza,ALIZADEH Mohammad Hassan.Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates[J].Chinese Journal of Chemistry,2007,25(9):1340-1343. |
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| Authors: | TAYEBEE Reza ;ALIZADEH Mohammad Hassan |
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| Institution: | [1]Department of Chemistry, Sabzevar University, Sabzevar, 397, lran; [2]Department of Chemistry, Ferdowsi University, Mashhad, 91779, lran |
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| Abstract: | An environmentally benign oxygenation protocol was developed for selective oxidation of some types of aromatic and aliphatic sulfides in good to excellent yields utilizing 34% hydrogen peroxide catalyzed by simple heteropolyoxometalates in normal drinking water at room temperature. The catalysts could be recovered and reused for at least seven reaction cycles under the described reaction conditions without considerable loss of reactivity. This procedure introduced a new insight into the use of simple heteropolyanions as recoverable catalysts for the oxidation of organic sulfides by an environmentally acceptable protocol. Keywords |
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| Keywords: | oxidation heteropolyacid catalysis hydrogen peroxide organic sulfide |
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