| Rapid Thermolysis Studies of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O and Cd（CHZ）2（TNR）（H2O） |
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| 引用本文： | 左小丽 乔小晶 孙远华 张同来 张建国 杨利 王绍宗. Rapid Thermolysis Studies of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O and Cd（CHZ）2（TNR）（H2O）[J]. 中国化学, 2007, 25(7): 06-909. DOI: 10.1002/cjoc.200790175 |
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| 作者姓名： | 左小丽 乔小晶 孙远华 张同来 张建国 杨利 王绍宗 |
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| 作者单位： | State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20471008）. |
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| 摘 要： | T-jump/FT-IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O and Cd（CHZ）2（TNR）（H2O） under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O are NH3, H2O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd（CHZ）2（TNR）（H2O）. Thus Cd（CHZ）2（TNR）（H2O） is not an eco-friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb2（TNR）2（CHZ）2（H2O）2].4H2O is higher than that of Cd（CHZ）2（TNR）（H2O）, there is no HNCO in the combus- tion products and the amount of NO is less than the experiment result from T-jump/FTIR.
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| 关 键 词： | 铬络合物 真密码 铅络合物 光谱学 |
| 修稿时间： | 2006-10-16 |
Rapid Thermolysis Studies of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O and Cd（CHZ）2（TNR）（H2O） |
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| ZUO Xiao-Li,QIAO Xiao-Jing, SUN Yuan-Hua,ZHANG Tong-Lai, ZHANG Jian-Guo,YANG Li, WANG Shao-Zong. Rapid Thermolysis Studies of [Pb2（TNR）2（CHZ）2（H2O）2]·4H2O and Cd（CHZ）2（TNR）（H2O）[J]. Chinese Journal of Chemistry, 2007, 25(7): 06-909. DOI: 10.1002/cjoc.200790175 |
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| Authors: | ZUO Xiao-Li QIAO Xiao-Jing SUN Yuan-Hua ZHANG Tong-Lai ZHANG Jian-Guo YANG Li WANG Shao-Zong |
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| Affiliation: | State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | T‐jump/FT‐IR spectroscopy was used to study the rapid thermal decomposition activity of [Pb2(TNR)2(CHZ)2(H2O)2]·4H2O and Cd(CHZ)2(TNR)(H2O) under 0.1 MPa Ar atmosphere. The results show that the main gaseous products of [Pb2(TNR)2(CHZ)2(H2O)2]·4H2O are NH3, H2O and HONO, while CO and NO are the major gaseous products of flash pyrolysis of Cd(CHZ)2(TNR)(H2O). Thus Cd(CHZ)2(TNR)(H2O) is not an eco‐friendly and chemically compatible primary explosive. Both compounds liberate volatile metal carbonate, oxide and isocyanate compounds. The combustion temperature and products of the two compounds were calculated by Real code. The results of theoretical calculation show that the combustion temperature of [Pb2(TNR)2(CHZ)2(H2O)2]·4H2O is higher than that of Cd(CHZ)2(TNR)(H2O), there is no HNCO in the combustion products and the amount of NO is less than the experiment result from T‐jump/FTIR. |
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| Keywords: | T-jump/FTIR lead complex chromium complex Real code |
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