| Crystal Structure, Thermal Stability and Luminescence of Coordination Polymer [Cd（BBP）（p-PDOA）]n |
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| 引用本文： | 杨燕 曾明华 张淑华 梁宏. Crystal Structure, Thermal Stability and Luminescence of Coordination Polymer [Cd（BBP）（p-PDOA）]n[J]. 中国化学, 2007, 25(8): 1121-1125. DOI: 10.1002/cjoc.200790209 |
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| 作者姓名： | 杨燕 曾明华 张淑华 梁宏 |
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| 作者单位： | [1]School of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, China [2]School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, China [3]Department of Chemistry and Biology, Yulin Teachers＇ College, Yulin, Guangxi 537000, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （Nos. 30460153, 20561001） and the Natural Science Foundation of Guangxi Province （No. 0447019）. |
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| 摘 要： | Hydrothermal reaction of Cd（NO3）2·4H2O with bbp and p-PDOAH2 at 140 ℃ yielded a novel 1D cadmium（Ⅱ） coordination polymer, [Cd（bbp）（p-PDOA）]n （bbp=2,6-bis（benzimidazol-2-yl）pyridine, p-PDOA=p-phenylenedioxydiacetate dianion）, in which CdN3O4 pentagonal bipyramids were linked by p-PDOA ligands in a bis-bidentate mode to construct a zigzag chain with the adjacent Cd…Cd distance of 1.14（1） nm, There exists a 2D supramolecular network linked by π-π stacking with a face-to-face distance of 0.35（1） nm between the 2,6-bis（benzimidazol-2-yl） pyridine ligands and hydrogen-bonding interactions （0.27（4） nm）. A 3D supramolecular network was further constructed by these non-covalent interactions between the zippers. The TG/DTG showed that its chain skeleton was thermally stable up to 389 ℃ and the blue fluorescent emission of the complex was determined at 428 nm in a solid state with its long decay lifetime of 7.24 ns.
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| 关 键 词： | 镉配合物 晶体结构 发光性质 热稳定性 |
| 修稿时间： | 2007-04-252007-07-02 |
Crystal Structure,Thermal Stability and Luminescence of Coordination Polymer [Cd(BBP)(p‐PDOA)]n |
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| YANG Yan,ZENG Ming-Hua, ZHANG Shu-Hua,LIANG Hong. Crystal Structure,Thermal Stability and Luminescence of Coordination Polymer [Cd(BBP)(p‐PDOA)]n[J]. Chinese Journal of Chemistry, 2007, 25(8): 1121-1125. DOI: 10.1002/cjoc.200790209 |
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| Authors: | YANG Yan ZENG Ming-Hua ZHANG Shu-Hua LIANG Hong |
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| Affiliation: | 1. School of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, China;2. School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, China;3. Department of Chemistry and Biology, Yulin Teachers' College, Yulin, Guangxi 537000, China |
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| Abstract: | Hydrothermal reaction of Cd(NO3)2·4H2O with bbp and p‐PDOAH2 at 140 °C yielded a novel 1D cadmium(II) coordination polymer, [Cd(bbp)(p‐PDOA)]n (bbp?2,6‐bis(benzimidazol‐2‐yl)pyridine, p‐PDOA?p‐phenylenedioxy‐ diacetate dianion), in which CdN3O4 pentagonal bipyramids were linked by p‐PDOA ligands in a bis‐bidentate mode to construct a zigzag chain with the adjacent Cd···Cd distance of 1.14(1) nm. There exists a 2D supramolecular network linked by π‐π stacking with a face‐to‐face distance of 0.35(1) nm between the 2,6‐bis(benzimidazol‐2‐yl) pyridine ligands and hydrogen‐bonding interactions (0.27(4) nm). A 3D supramolecular network was further constructed by these non‐covalent interactions between the zippers. The TG/DTG showed that its chain skeleton was thermally stable up to 389 °C and the blue fluorescent emission of the complex was determined at 428 nm in a solid state with its long decay lifetime of 7.24 ns. |
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| Keywords: | cadmium complex crystal structure luminescent property |
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