| Synthesis of an Anionic Receptor Based on Phenylhydrazone Group and Its Recognition Property for Acetate |
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| 作者姓名： | 王月红 林海 林华宽 |
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| 作者单位： | [1]Department of Chemistry, Nankai University, Tianjin 300071, China [2]Key Laboratory of Functional Polymer Materials of Ministry of Education, Nankai University, Tianjin 300071, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20371028, 20671052） and the Natural Science Foundation of Tianjin of China （No. 023605811）. |
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| 摘 要： | A colorimetric anion receptor was synthesized by a simple method where the phenylhydrazone moiety was need as binding sites. The anion recognition via hydrogen-bonding interactions can be easily monitored by anion complexation induced changes in UV-vis absorption spectra. Moreover, the hydrogen bond formation between the phenylhydrazone N-H and acetate or fluoride anion was described on the basis of ^1H NMR experiments.
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| 关 键 词： | 阴离子受体 苯腙 醋酸盐 比色识别 氢键 |
| 修稿时间： | 2007-03-05 |
Synthesis of an Anionic Receptor Based on Phenylhydrazone Group and Its Recognition Property for Acetate |
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| WANG, Yue-Hong LIN, Hai LIN, Hua-Kuan.Synthesis of an Anionic Receptor Based on Phenylhydrazone Group and Its Recognition Property for Acetate[J].Chinese Journal of Chemistry,2007,25(10):1430-1433. |
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| Authors: | WANG Yue-Hong LIN Hai LIN Hua-Kuan |
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| Institution: | a Department of Chemistry, Nankai University, Tianjin 300071, China; b Key Laboratory of Functional Polymer Materials of Ministry of Education, Nankai University, Tianjin 300071, China |
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| Abstract: | A colorimetric anion receptor was synthesized by a simple method where the phenylhydrazone moiety was need as binding sites. The anion recognition via hydrogen-bonding interactions can be easily monitored by anion complexation induced changes in UV-vis absorption spectra. Moreover, the hydrogen bond formation between the phenylhydrazone N-H and acetate or fluoride anion was described on the basis of ^1H NMR experiments. |
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| Keywords: | receptor phenylhydrazone anion colorimetric recognition hydrogen bond |
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