| N-Heterocyclic Carbene-Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas |
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| 引用本文： | 郑书展 彭新高 刘建明 孙伟 夏春谷. N-Heterocyclic Carbene-Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas[J]. 中国化学, 2007, 25(8): 1065-1068. DOI: 10.1002/cjoc.200790196 |
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| 作者姓名： | 郑书展 彭新高 刘建明 孙伟 夏春谷 |
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| 作者单位： | [1]State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academic of Sciences, Lanzhou, Gansu 730000, China [2]Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （Nos. 20533080, 20625308）. |
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| 摘 要： | Palladium carbene shows high efficiency without any promoter on oxidative carbonylation of amines to ureas and a new type of palladium carbene complex containing both an aniline and an NHC ligands was found to be the active species for the reaction.
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| 关 键 词： | N-杂环碳烯 氧化羰基化 尿素 胺 |
| 修稿时间： | 2007-01-312007-06-20 |
N-Heterocyclic Carbene-Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas |
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| ZHENG Shu-Zhan, PENG Xin-Gao,LIU Jian-Ming, SUN wei, XIA Chun-Gu. N-Heterocyclic Carbene-Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas[J]. Chinese Journal of Chemistry, 2007, 25(8): 1065-1068. DOI: 10.1002/cjoc.200790196 |
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| Authors: | ZHENG Shu-Zhan PENG Xin-Gao LIU Jian-Ming SUN wei XIA Chun-Gu |
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| Affiliation: | 1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academic of Sciences, Lanzhou, Gansu 730000, China ;2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| Abstract: | Palladium carbene shows high efficiency without any promoter on oxidative carbonylation of amines to ureas and a new type of palladium carbene complex containing both an aniline and an NHC ligands was found to be the active species for the reaction. |
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| Keywords: | N-heterocyclic carbene oxidative carbonylation urea |
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