| Abstract: | Drastic changes occur during the initial stages of the α-olefin polymerization over heterogeneous catalysts. Fragmentation of the support takes place as polymer is formed at the active sites within the voids of the support/catalyst. Magnesium chloride-supported titanium catalyst/polymer particles have been analyzed employing high-resolution computed microtomography (CMT) using synchrotron radiation at Brookhaven National Laboratory. The changes in morphology, the spatial distribution of the support/catalyst fragments, porosity, and polymer distribution in single growing polypropylene and polyethylene particles have been studied. These studies documented considerable macroporosity ( > 2 μm in size) within the growing catalyst/support/polymer particles. The largest pores may be due to agglomeration of smaller subparticles. Our results confirm that the initial fragmentation of the support proceeds readily and uniformly to yield a multi-grain growth of subparticle agglomerates. The support/catalyst fragments appear to be distributed relatively uniformly within the growing polymer particle. The surface of the subparticle agglomerates is accessible through the void-space between growing catalyst/particle grains. This may facilitate monomer transport to the activate sites through the polymer/catalyst particles. © 1993 John Wiley & Sons, Inc. |
