Abstract: | A series of aliphatic and aromatic polytrithiocarbonates was prepared using a novel “one-pot” synthesis procedure employing a phase-transfer catalyst. The starting reagents were either an aliphatic or an aromatic dihalide and an excessive amount of carbon disulfide. The effects of the phase-transfer catalyst and reaction conditions on yield were studied. The structure and composition of the polymers and reaction side-products were determined from infrared, ultraviolet, 1H-NMR spectra, and elemental analyses. The polymers were further characterized by viscosity measurement and thermal analysis. © 1993 John Wiley & Sons, Inc. |