[Mo(NPPh3)4]2+ [MoNCl3(NPPh3)]2− · C7H8, ein Phosphaniminato-Komplex mit einem Dikation von Molybdän(VI) |
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Authors: | Dirk Nußhr Frank Weller Kurt Dehnicke |
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Institution: | Dirk Nußhär,Frank Weller,Kurt Dehnicke |
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Abstract: | Mo(NPPh3)4]2+ MoNCl3(NPPh3)]2? · C7H8, a Phosphoraneiminato Complex with a Dication of Molybdenum(VI). The title compound was prepared by the reaction of MoNCl3 with Me3SiNPPh3 in acetonitrile solution. Red single crystals separated upon addition of toluene. They were characterized by IR spectroscopy and by an X-ray structure determination. (Space group P1 , Z = 2, 6918 observed unique reflections, R = 0.059. Lattice dimensions at 20°C: a = 1 181.4, b = 2 021.4, c =2 409.7pm; α = 65.87°, β = 101.09°, γ= 78.97°). In the dication Mo(NPPh3)4]2+ the molybdenum atom is surrounded in a tetrahedral fashion by the four nitrogen atoms of the phosphorane iminato ligands. The MoN and PN bond lengths correspond well with double bonds. In the two anions MoNCl3(NPPh3)]?, which occur in different conformations, the molybdenum atoms are fivefold coordinated by the terminal nitride ligand Mo?N: in axial positions and by the three chlorine atoms and the nitrogen atom of the (NPPh3)? ligand in the equatorial positions. |
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Keywords: | Phosphoraneiminato Complex of Molybdenum Synthesis IR Spectrum Crystal Structure |
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