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Über die Darstellung der Dichlormethylen-halogensulfenium-Salze Cl2CSCl+ AsF6− und Cl2CSBr+ AsF6− [1] |
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| Authors: | R Minkwitz W Meckstroth |
| Abstract: | The Synthesis of the Dichloromethylene-halogenosulfenium Salts Cl2CSCl+ AsF6? and Cl2CSBr+ AsF6? The sulfenium salts Cl2CSCl+ AsF6? and Cl2CSBr+ AsF6? are synthesized by oxidative halogenation of thiophosgene, Cl2CS with X2/AsF5 (X = Cl, Br) at 195 K and are characterized by vibrational as well as NMR spectroscopy. |
| Keywords: | Sulfenium Salts Preparation Vibrational Spectra NMR-Spectra |