Chemie der Isoblausäure. VIII. Protonierung eines ‚mobilen’︁ Cyanoliganden: cis-[(μ-CNH2)Fe2Cp2(CO)3]X (X = Cl,BF4, PF6, I) |
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| Authors: | P Wolf Fehlhammer Fritz Schoder Gerhard Beck Stephan Schrlkamp |
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| Institution: | P. Wolf Fehlhammer,Fritz Schoder,Gerhard Beck,Stephan Schrölkamp |
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| Abstract: | Chemistry of Hydrogen Isocyanide. VIII. Protonation of a ‘Mobile’ Cyano Ligand: cis-μ-CNH2)Fe2Cp2(CO)3]X (X = Cl, BF4, PF6, I) . Protonation of the terminal cyano ligand in the complex cis-NaFe2(CN)Cp2(CO)3] affords the N-diprotonated produkt Fe2Cp2(CO)3(μ-CNH2)]+ X? (X = Cl, BF4, PF6, I) exclusively; the structure of the chloride has been determined by X-ray analysis. |
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| Keywords: | Diiron complexes aminocarbyne bridging ligand N-protonated hydrogen isocyanide X-ray structure |
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