Formation of nitrone in the reaction ofpara-nitroso-N,N-dimethylaniline with tetracyanoethylene |
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| Authors: | D. L. Lipilin A. M. Churakov S. L. Ioffe Yu. A. Strelenko V. A. Tartakovsky |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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| Abstract: | para-Nitroso-N,N-dimethylaniline reacts with tetracyanoethylene to give [4-(dimethyl-amino)phenylimino]malononitrileN-oxide 1 (65%) in addition to [4-(dimethyl-amino)phenylimino]malononitrile 2 (17%). The structures of the products are confirmed by spectral data and chemical transformations. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 617–619, March, 1997. |
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| Keywords: | aromatic nitroso compounds tetracyanoethylene nitrones cycloaddition reactions |
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