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Formation of nitrone in the reaction ofpara-nitroso-N,N-dimethylaniline with tetracyanoethylene
Authors:D L Lipilin  A M Churakov  S L Ioffe  Yu A Strelenko  V A Tartakovsky
Institution:(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
Abstract:para-Nitroso-N,N-dimethylaniline reacts with tetracyanoethylene to give 4-(dimethyl-amino)phenylimino]malononitrileN-oxide 1 (65%) in addition to 4-(dimethyl-amino)phenylimino]malononitrile 2 (17%). The structures of the products are confirmed by spectral data and chemical transformations. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 617–619, March, 1997.
Keywords:aromatic nitroso compounds  tetracyanoethylene  nitrones  cycloaddition reactions
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