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Anhydro bases of 3-pyridylindoles
Authors:T. V. Stupnikova  B. P. Zemskii  Yu. B. Vysotskii  R. S. Sagitullin  Kh. Ya. Lopatinskaya
Affiliation:(1) Donetsk State University, 340055 Donetsk;(2) M. V. Lomonosov Moscow State University, 117234 Moscow
Abstract:The reactions of quaternary salts of 3-pyridyl- and benzopyridylindoles with alkali proceed via two pathways, viz., deprotonation, the products of which are anhydro bases, and dealkylation of the pyridine ring, as a consequence of which the corresponding nonquaternized bases are formed. The reactions are interpreted from a quantum-chemical point of view.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 959–964, July, 1980.
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