Photosensitivity of methylene chloride,stimulated by free radicals |
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| Authors: | Yu A Mikheev V P Pustoshnyi D Ya Toptygin |
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| Institution: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The direct photolysis of CH2C12 leads to the formation of HC1 and unsaturated compounds with conjugated C=C bonds. These same products are also formed under the influence of light that is not absorbed by CH2C12 ( > 290 nm) in the presence of initiators of free radical reactions: benzoyl peroxide, benzophenone, anthraquinone, and Fe3+ chlorides.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2094–2097, September, 1976. |
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