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Miscibility of poly(vinyl chloride) with chitin derivatives having poly(2-methyl-2-oxazoline) side chains
Authors:Keigo Aoi  Akinori Takasu  Masahiko Okada
Abstract:Binary blends of poly(vinyl chloride) (PVC) and chitin-graft-poly(2-methyl-2-oxazoline) showed miscibility in the blend fraction range of the latter lower than ca. 10 wt.-%. The glass transition temperature of PVC, which was determined by differential scanning calorimetry, changed to lower temperatures with increasing modified chitin contents up to 10 wt.-%. Segmental interaction between PVC and the graft copolymer was confirmed by the carbonyl stretching band shift in the FT-IR analysis.
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