Trindenyl[tris(rheniumtricarbonyl)] |
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| Institution: | 1. State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, 100083 Beijing, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Department of Physics, Division of Science and Technology, University of Education, College Road, Township, Lahore, Pakistan;4. Advanced Functional Materials & Optoelectronics Laboratory (AFMOL), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia;5. Department of Physics, The University of Lahore, Pakistan;6. School of Science, Minzu University of China, Beijing 100081, China;1. Organic & Biomolecular Chemistry Division, CSIR—Indian Institute of Chemical Technology, Hyderabad 500 607, India;2. Division of Natural Products Chemistry, CSIR—Indian Institute of Chemical Technology, Hyderabad 500 607, India;1. Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551, Japan;2. Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba 277-8581, Japan;3. Department of Physics, Sophia University, Chiyoda-ku, Tokyo 102-8554, Japan;1. Max Planck Institute for Solid State Research, Heisenbergstraße 1, 70569 Stuttgart, Germany;2. Institut de Physique de la Matière Condensée, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland;3. University Erlangen-Nürnberg, Institut für Organische Chemie, Henkestr. 42, 91054 Erlangen, Germany;1. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China;3. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;4. Network and Information Center, Dalian University of Technology, Dalian 116024, China |
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| Abstract: | Trindene is combined with KH and Re(CO)3(THF)Br]2 (THF = tetrahydrofuran) in THF to yield the first trinuclear half-sandwich complex of the trindene trianion, (trindenyl)Re(CO)3]3, in 50% yield. Two of the rhenium carbonyl units are rigidly held in close proximity and the carbonyl ligands on adjacent metals are vibrationally coupled. Both cis and trans isomers of the dirhenium complex, (trindenyl)Re(CO)3]2, are also isolated from the above reaction in low yield. |
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