A new approach to the coordination of anions,novel polycobalticinium macrocyclic receptor molecules |
| |
| Affiliation: | 1. University of Hawaii – Manoa, Department of Chemistry, 2545 McCarthy Mall, Honolulu, HI 96822-2275, Unites States;2. Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185-1411, Unites States;3. Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185-0886, Unites States;4. Sandia National Laboratories, Advanced Materials Laboratory, 1001 University Boulevard, SE, Albuquerque, NM 87106, Unites States;1. State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;2. Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, Guangxi Key Laboratory of Information Material, School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China;1. Department of Chemical Engineering, University of Illinois at Chicago, 810 S. Clinton St., Chicago, IL 60607, United States;2. Department of Civil and Environmental Engineering and Villanova Center for the Advancement of Sustainable Engineering (VCASE), Villanova University, Villanova, PA 19085, United States;1. Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, PR China;2. School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, PR China;1. Università di Pisa, Dipartimento di Chimica e Chimica Industriale, Via G. Moruzzi 13, I-56124 Pisa, Italy;2. Dipartimento di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4, I-40136 Bologna, Italy |
| |
| Abstract: | The syntheses and electrochemistry of four novel polycobalticinium macrocyclic receptor molecules are reported. Preliminary anion coordination studies in one case reveal the receptor to be redox responsive to the binding of a Br− guest anion, shifting the respective cobalticinium reduction wave to more negative potentials. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
