Trimethylaluminum mediated halomethylation of [(arene)2Fe]2+ cations |
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| Institution: | 1. Department of Chemistry, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh;2. Department of Chemical and Pharmaceutical Sciences, Via L. Giorgieri 1, Trieste 34127, Italy;3. College of Science, King Saud University, Riyadh 11451, Saudi Arabia;4. Department of Physics and Astronomy, College of Science, King Saud University, Riyadh 11451, Saudi Arabia;5. Department of Physics, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh;6. Department of Applied Science, Faculty of Science, Okayama University of Science, Japan;7. Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan;8. Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh;9. Biochemistry and Molecular Biology, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh |
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| Abstract: | The arene salts (arene)2Fe](PF6)2 (arene = mesitylene 1a, and hexamethylbenzene, 1c) react readily with AlMe3 in dichloromethane or dibromomethane to produce the novel exo-halomethyl-η5-cyclohexadienyl salts (η5-exo-CH2XC6H3Me3)(η6-C6H3Me3)Fe]PF6 (X = Cl, 2d; X = Br, 2e) and (η5-exo-CH2XC6Me6)(η6-C6Me6)Fe]PF6 (X = Cl, 2f; X = Br, 2g) which have been characterized spectroscopically and, in the case of 2f, crystallographically. |
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