Arylation of a carbanion derived from a pyridazine; a route to a functionalized aren |
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| Affiliation: | 1. Jiangsu Key Laboratory of Bioactive Natural Product Research and State Key Laboratory of Natural Medicines, Department of Natural Medicinal Chemistry, School of Traditional Chinese Pharmacy, China Pharmaceutical University, 24 Tong Jia Xiang, Nanjing 210009, People’s Republic of China;2. State Key Laboratory of Pharmaceutical Biotechnology, Nanjing University, Nanjing 210093, People’s Republic of China;3. School of Chemistry & Environmental Engineering, Jiangsu University of Technology, 1801 Zhongwu Rd., Changzhou, Jiangsu 213001, People’s Republic of China;4. The Joint Research Centre of Gene Interference, Guangzhou University and Keele University for Gene Interference and Application, School of Life Science, Guangzhou University, 230 Waihuan West Road, Guangzhou 510006, People’s Republic of China;1. Syngenta Crop Protection AG, Crop Protection Research, Research Chemistry, Schaffhauserstrasse 101, CH-4332, Switzerland;2. Bogazici University, Department of Chemistry, Bebek, 34342 Istanbul, Turkey;1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmans’ka Str. 5, Kyiv 02094, Ukraine;2. ChemBioCenter, Kyiv National Taras Shevchenko University, Chervonotkatska Street 61, Kyiv 02094, Ukraine;3. Enamine Ltd, Matrosova Street 23, Kyiv 01103, Ukraine;4. Bâtiment Lavoisier, Université de Versailles-Saint-Quentin, 45 avenue des Etats-Unis, 78035 Versailles, France;5. Université de Tours (UFR Sciences & Techniques), INRA Nouzilly—UMR1282 Infectiologie et Santé Publique, F-37000 Tours, France;1. Qiqihar University, Qiqihar 161006, PR China;2. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China |
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| Abstract: | 1,4-Dichlorobenzene(cyclopentadienyl)iron(II) hexafluorophosphate reacts with the carbanion derived from 3-ethoxy-6-methylpyridazine N-oxide to give a Yanovsky-type adduct. |
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