Synthesis of the cyanamide-derived bis(cyanoimido) complexes trans-[M(NCN)2(Ph2PCH2CH2PPh2)2] (M = Mo or W) and crystal structure of the molybdenum compound |
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| Institution: | 1. Department of Applied Chemistry, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China;2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China;1. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, PR China;2. Hunan Key Laboratory for Super-microstructure and Ultrafast Process, School of Physics and Electronics, Central South University, Changsha, Hunan 410083, PR China;3. College of Electrical and Information Engineering, Hunan Institute of Engineering, Xiangtan 411101, PR China |
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| Abstract: | Reaction of cyanamide (NCNH2) with trans-M(N2)2(dppe)2] (M = Mo or W, dppe = PH2PCH2CH2PPh2) leads to the formation of the bis(cyanoimido) complexes trans-M(NCN)2(dppe)2]. The crystal structure of trans-Mo(NCN)2(dppe)2] has been determined by an X-ray diffraction study. |
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