Abstract: | Certain metal-catalyzed hydrosilations have been found to occur in a highly regioselective manner which makes them useful for the preparation of unique classes of ambifunctional monomers. These monomers bear two chemically different functional groups within the same molecule. By selection of the appropriate functional groups it is possible to design monomers in which the functional groups react independently, copolymerize, or polymerize by different mechanisms. This article describes some recent results of the synthesis and polymerization of several novel types of ambifunctional monomers. |